Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00049772" target="_blank" >RIV/00216224:14310/11:00049772 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.poly.2011.03.027" target="_blank" >http://dx.doi.org/10.1016/j.poly.2011.03.027</a>

DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands

Original language description

Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2)2Clx(NO3)2-x][FeCl4] and [Ln(dppdO2)2(NO3)2]NO3, where dppfO2 and dppdO2 are bis(diphenylphosphoryl) ferrocene and bis(diphenylphosphoryl)diphenyl ether, respectively. Reactions of the rigid bis(diphenylphosphoryl)benzene (dppbO2) with lanthanide salts yielded linear coordination polymers of a 1:1.5 metal-to-ligand stoichiometry. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, mass spectrometry, and TG/DSC techniques.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F08%2F1111" target="_blank" >GA203/08/1111: Synthesis and properties of inorganic-organic polymeric materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

30

Issue of the periodical within the volume

9

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

1620-1627

UT code for WoS article

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EID of the result in the Scopus database

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