Aluminum(III) chloride-alkoxides as molecular precursors for alumina
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00049935" target="_blank" >RIV/00216224:14310/11:00049935 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Aluminum(III) chloride-alkoxides as molecular precursors for alumina
Original language description
The reactions of dichloroethylalane with selected alcohols and phenols afforded a series of six new crystalline aliminum(III) chloride-alkoxides which were structurally characterized by the single crystal X-ray diffraction analysis. The prepared molecules display, depending on the steric properties of employed substituents and the reaction and crystallization conditions, a large structural variability. These compounds are by virtue of their composition suitable single-source precursors for alumina. Therefore the transformations of aluminum(III) chloride-alkoxides to aluminum(III) oxide was performed by solution thermolysis in a high-boiling solvent. The reactions are based on alkylhalide elimination which was proved by indentifying byproducts by gas chromatography-mass spectrometry.
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů