Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00050014" target="_blank" >RIV/00216224:14310/11:00050014 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/11:00367143
Result on the web
<a href="http://pubs.acs.org/doi/abs/10.1021/jp205218k?prevSearch=%255BContrib%253A%2Bsvec%255D&searchHistoryKey=" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/jp205218k?prevSearch=%255BContrib%253A%2Bsvec%255D&searchHistoryKey=</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jp205218k" target="_blank" >10.1021/jp205218k</a>
Alternative languages
Result language
angličtina
Original language name
Anion Binding by Bambus[6]uril Probed in the Gas Phase and in Solution
Original language description
Electrospray ionization mass spectrometry (ESI-MS) is used to probe the binding of small anions to the macrocycle of bambus[6]uril. For the halide ions, the experimental patterns suggest F? < Cl? < Br? < I?, which is consistent with the order ofanion binding found in the condensed phase. Parallel equilibrium studies in the condensed phase establish the association constants of halide anions and bambus[6]uril in mixed solvents. A detailed analysis of the mass spectrometric data is used to shedlight on the correlations between the binding constants in the condensed phase and the ion abundances observed using ESI-MS. From the analysis it becomes apparent that ESI-MS can indeed represent the situation in solution to some extent, but the samplingin the gas-phase experiment is not 1:1 compared to that in solution.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
J. Phys. Chem. A
ISSN
1089-5639
e-ISSN
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Volume of the periodical
115
Issue of the periodical within the volume
41
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
11378-11386
UT code for WoS article
000295700600029
EID of the result in the Scopus database
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