Glycoluril Dimer Isomerization under Aqueous Acidic Conditions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00062306" target="_blank" >RIV/00216224:14310/12:00062306 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/abs/10.1021/jo302063j" target="_blank" >http://pubs.acs.org/doi/abs/10.1021/jo302063j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jo302063j" target="_blank" >10.1021/jo302063j</a>
Alternative languages
Result language
angličtina
Original language name
Glycoluril Dimer Isomerization under Aqueous Acidic Conditions
Original language description
A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is the only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. Compound 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to those for cucurbituril synthesis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ED0001%2F01%2F01" target="_blank" >ED0001/01/01: CETOCOEN</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
The Journal of Organic Chemistry
ISSN
0022-3263
e-ISSN
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Volume of the periodical
77
Issue of the periodical within the volume
23
Country of publishing house
US - UNITED STATES
Number of pages
4
Pages from-to
10945-10948
UT code for WoS article
000311926100051
EID of the result in the Scopus database
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