Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00064415" target="_blank" >RIV/00216224:14310/12:00064415 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.2465/jmps.110930" target="_blank" >http://dx.doi.org/10.2465/jmps.110930</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.2465/jmps.110930" target="_blank" >10.2465/jmps.110930</a>
Alternative languages
Result language
angličtina
Original language name
Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O
Original language description
Bukovskyite is a relatively rare secondary ferric arsenate-sulfate. At the type locality near the municipality of Kutna Hora (Czech Republic), it is the main secondary mineral in the medieval dumps, where it occurs in enormous amounts and forms nodules of prodigious dimensions. We investigated the mineral bukovskyite and the type locality in detail to understand the abundance of the mineral at this locality. The crystal structure of bukovskyite was solved for bukovskyite crystals from Grossvoigtsberg (Germany) and found to be of the space group P (I) over bar with a final R factor of 5.08% from 2403 reflections. The lattice parameters at room temperature are a = 7.549(1) angstrom, b = 10.305(1) angstrom, c = 10.914(2) angstrom, alpha = 115.136(3)degrees, beta = 99.798(3)degrees, and gamma = 92.864(3)degrees. The structure consists of octahedral-tetrahedral Fe-arsenate chains. Sulfate tetrahedra are bonded to the chains and free H2O molecules via a complicated network of hydrogen bonds.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
DB - Geology and mineralogy
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES
ISSN
1345-6296
e-ISSN
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Volume of the periodical
107
Issue of the periodical within the volume
3
Country of publishing house
JP - JAPAN
Number of pages
16
Pages from-to
133-148
UT code for WoS article
000306347700003
EID of the result in the Scopus database
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