A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00080729" target="_blank" >RIV/00216224:14310/15:00080729 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/anie.201409895/abstract;jsessionid=ABCDEB2B3122226D3B80E184E66BCDB5.f02t03" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/anie.201409895/abstract;jsessionid=ABCDEB2B3122226D3B80E184E66BCDB5.f02t03</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201409895" target="_blank" >10.1002/anie.201409895</a>

Result language
angličtina
Original language name
A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity
Original language description
Synthetic receptors that function in water are important for the qualitative and quantitative detection of anions, which may act as pollutants in the environment or play important roles in biological processes. Neutral receptors are particularly appealing because they are often more selective than positively charged receptors; however, their affinity towards anions in pure water is only in range of 1-10(3)Lmol(-1). The anion-templated synthesis of a water-soluble bambusuril derivative is shown to be anoutstanding receptor for various inorganic anions in pure water, with association constants of up to 10(7)Lmol(-1). Furthermore, the macrocycle discriminates between anions with unprecedented selectivity (up to 500000-fold). We anticipate that the combination of remarkable affinity and selectivity of this macrocycle will enable the efficient detection and isolation of diverse anions in aqueous solutions, which is not possible with current supramolecular systems.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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