On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00082257" target="_blank" >RIV/00216224:14310/15:00082257 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0277538714005440" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0277538714005440</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2014.08.022" target="_blank" >10.1016/j.poly.2014.08.022</a>

Result language
angličtina
Original language name
On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part IV: Reactions with thiosemicarbazide monoaryl derivatives
Original language description
In connection with our previous research, reactions of chlorodithiophosphoric acid pyridiniumbetaine, py.PS2Cl (I), with monoaryl thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = phenyl, 4-nitrophenyl) were studied with the aim to prepare new heterocyclic compounds. All reactions were carried out in acetonitrile in the presence of pyridine as an HCl acceptor. New compounds, pyridinium salts of 4-phenyl-3-sulfido-3,5-dithioxo-1,2,4,3k5-triazaphospholidine (II) and 4-(4-nitrophenyl)-3-sulfido-3, 5-dithioxo-1,2,4,3k5-triazaphospholidine (III) were prepared. 31P NMR, FT-IR, Raman spectroscopy, and X-ray diffraction analysis revealed their molecular structures consisting of pyridinium cation and fivemembered P?N?N?C?N heterocyclic anion bearing relevantaryl group.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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