On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part III: Reactions with monoalkylderivatives of thiosemicarbazide

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F05%3A00013951" target="_blank" >RIV/00216224:14310/05:00013951 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

On the reactions of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part III: Reactions with monoalkylderivatives of thiosemicarbazide

Original language description

Reactions of chlorodithiophosphoric acid pyridinium betaine, py.PS2Cl, (I) with monosubstituted thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = methyl, ethyl), in acetonitrile media and in the presence of pyridine as an HCl acceptor were studied. New five-membered heterocyclic compounds were prepared, pyridinium salts of 4-methyl-3-sulfido-3,5-dithioxo-1,2,4,3-triazaphospholidine (II) and 4-ethyl-3-sulfido-3,5-dithioxo-1,2,4,3-triazaphospholidine (III). The substances II and III were completely characterized by 31P NMR, FT-IR, Raman spectroscopies and their molecular structures were determined by the X-ray diffraction analysis.

Czech name

K reakci pyridiniumbetainu kyseliny chlorodithiofosforecne s polyfunkcními nukleofily. Část III:Reakce s monoalkylderivátyy thiosemikarbazidu

Czech description

Byla studov&aacute;na reakce pyridiniumbetainu kyseliny chlorodithiofosforen&eacute; s monosubstituovan&yacute;mi deriv&aacute;ty (methyl, ethyl) thiosemikarbazidu v acetonitriku za p&iacute;tomnosti akceptoru HCl. Byly pipraveny nov&eacute; heterocyklick&eacute; sloueniny s ptietn&yacute;m cyklem.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2005

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

24

Issue of the periodical within the volume

14

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

6

Pages from-to

1855-1860

UT code for WoS article

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EID of the result in the Scopus database

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