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The use of flower-like gold nanoparticles in time-of-flight mass spectrometry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00082770" target="_blank" >RIV/00216224:14310/15:00082770 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The use of flower-like gold nanoparticles in time-of-flight mass spectrometry

  • Original language description

    Various types of gold nanoparticles (AuNPs) represent promising tools in many biomedical applications.[1-2] Here we report the first use of flower-like (FL) AuNPs as a mediator enhancing ionization in mass spectrometry (MS) of biomolecules. The main objective was to determine the effect of FL AuNPs on the ionization of biomolecules by surface assisted and matrix assisted laser desorption ionization (SALDI and MALDI) MS with time-of-flight analyzer. FL AuNPs alone or combined with cyano-4-hydroxycinnamicacid (CHCA) for MS measurement of peptides (500-3 500 m/z) were used. The comparison with classical CHCA matrix shows that FL AuNPs increase the ionization (~ 7.5 x) of peptides both alone and in combination with CHCA matrix. For ionization of higher mass peptides/proteins and those from mouse embryonic fibroblast (MEF) cells, FL AuNPs combined with CHCA and sinapinic acid (SA) were used.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/EE2.3.20.0185" target="_blank" >EE2.3.20.0185: Centre for analysis and modeling of tissues and organs</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů