Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F16%3A00094202" target="_blank" >RIV/00216224:14310/16:00094202 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/10426507.2015.1128922" target="_blank" >http://dx.doi.org/10.1080/10426507.2015.1128922</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/10426507.2015.1128922" target="_blank" >10.1080/10426507.2015.1128922</a>

Result language
angličtina
Original language name
Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles
Original language description
A series of six-membered Cu-I true heterocycles was prepared by reactions of Cu(PPh3)(2)NO3 with deprotonated R2P(S)-NH-C(O)R' (R' = (CH2)(3)CH3, C6H5, C6H4F, C6H4Cl; R = Ph, OPh) ligands. The synthesized compounds were characterized by P-31 NMR spectroscopy and single crystal X-ray diffraction. According to quantum chemical calculations, most of the true Cu-I heterocycles with the P-N-C ligands should be tetrahedral. However, an exceptional trigonal complex was observed upon crystallization.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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