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Synthesis of Pt(II) phosphinocarboxylate complexes with auxiliary arylcarbene ligands and factors that control their stereochemistry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F23%3A10469886" target="_blank" >RIV/00216208:11310/23:10469886 - isvavai.cz</a>

  • Result on the web

    <a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=VWWDHdoqJc" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=VWWDHdoqJc</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d3nj03729k" target="_blank" >10.1039/d3nj03729k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis of Pt(II) phosphinocarboxylate complexes with auxiliary arylcarbene ligands and factors that control their stereochemistry

  • Original language description

    Orthoplatinated complexes [Pt(C^C*)(acac)] (1 (R)), in which C&lt;^&gt;C* is orthoplatinated 3-R-1-phenyl-1H-benzo[d]imidazol-2-ylidene and R = Me and Ph, reacted with 1&apos;-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) under protonation of the acetylacetonate ligand (acac) to produce the corresponding phosphinocarboxylate bischelate complexes [Pt(C^C*)(dpf-kappa O-2,P)] (2(R)) as single isomers with trans-P,C(carbene) geometry. The compounds were fully characterized by elemental analysis, spectroscopic methods, single-crystal X-ray diffraction analysis, and cyclic voltammetry. In addition, DFT calculations were used to determine differences in energy and the bonding situation between 2(R) and the hypothetical geometric isomers 3(R) with a trans-P,C(phenyl) arrangement. The experimental and theoretical results are consistent with the antisymbiosis effect observed in complexes of soft metal ions, namely with weakening of Pt-C bonds by strongly trans-influencing ligands.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    New Journal of Chemistry

  • ISSN

    1144-0546

  • e-ISSN

    1369-9261

  • Volume of the periodical

    47

  • Issue of the periodical within the volume

    39

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    18442-18449

  • UT code for WoS article

    001076682400001

  • EID of the result in the Scopus database

    2-s2.0-85173881335