Multiple isomerism (cis/trans; syn/anti) in [(dmso)2Pt(aryl)2] complexes: A combined structural, spectroscopic, and theoretical investigation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F05%3A00023517" target="_blank" >RIV/61388955:_____/05:00023517 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Multiple isomerism (cis/trans; syn/anti) in [(dmso)2Pt(aryl)2] complexes: A combined structural, spectroscopic, and theoretical investigation
Original language description
The occurrence of cis or trans configurations in square planar diarylbis(dimethyl sulfoxide)platinum(II) complexes with S-bonded dmso ligands and aryl = 2,3,4,5,6-pentamethylphenyl, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2-, 3-, and 4-methylphenyl, and phenyl has been investigated by multinuclear (H-1, C-13, and Pt-195) NMR spectroscopy and crystal structure analysis. Both methods confirm the cis configuration for complexes with the smaller phenyl and methylphenyl (tolyl) ligands and the trans configuration for the compounds with the bulkier ligands, starting from 2,6-dimethylphenyl.
Czech name
Násobná izomerie (cis/trans; syn/anti) v [(dmso)2Pt(aryl)2] komplexech: Kombinovaný strukturní, spektroskopický a teoretický výzkum
Czech description
Výskyt cis or trans konfigurací ve čtvercově planárních diarylbis(dimethylsulfoxid)platina(II) komplexech se S-vázaným dimethylsulfoxidovým ligandem a aryl = 2,3,4,5,6-pentamethylphenyl-, 2,4,6-trimethylfenyl-, 2,6-dimethylfenyl-, 2-, 3- and 4-methylfenyl a fenyl byly zkoumány násobnou (1H, 13C and 195Pt) NMR spektroskopií a krystalově strukturní analýzou. Obě metody ve shodě s DFT výpočty potvrdily cis konfiguraci pro komplexy s menšími fenylovými a methylfenylovými (tolyl) ligandy a trans konfiguracipro sloučeniny s objemnými ligandy, počínaje 2,6-dimethylfenylem.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
24
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
4125-4131
UT code for WoS article
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EID of the result in the Scopus database
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