Synthesis and bonding in platinum(II) complexes with cyclometalated carbene and isoelectronic bis(phosphino)metallocene ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F24%3A10483840" target="_blank" >RIV/00216208:11310/24:10483840 - isvavai.cz</a>

Result on the web

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.pRtaFoEO6" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.pRtaFoEO6</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2024.123236" target="_blank" >10.1016/j.jorganchem.2024.123236</a>

Result language

angličtina

Original language name

Synthesis and bonding in platinum(II) complexes with cyclometalated carbene and isoelectronic bis(phosphino)metallocene ligands

Original language description

Four cycloplatinated complexes of the type [Pt(C^C*){M(η(5)-C5H4PPh2)2-κ(2)P,P&apos;}][PF6]n (M = Fe, n =1; M = Co, n = 2), where C^C* is 2-(3-methylimidazol-2- ylidene-1-yl-κC2)phenyl-κC1 and similar cyclometalated ligands bearing an additional aromatic ring and phenyl substituents at the imidazol-2-ylidene unit, were prepared and structurally characterized by spectroscopic methods (NMR and ESI MS), elemental analysis, cyclic voltammetry and DFT calculations. Experimental structural parameters and DFT calculations consistently indicate differentiation of the Pt-bound phosphine groups due to unlike trans influence of the phenyl and carbene donor moieties at the cyclometalated ligand in these compounds

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

—

Continuities

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2024

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

1872-8561

Volume of the periodical

1015

Issue of the periodical within the volume

July

Country of publishing house

CH - SWITZERLAND

Number of pages

8

Pages from-to

123236

UT code for WoS article

001294701200001

EID of the result in the Scopus database

2-s2.0-85196284231