Efficient synthesis of alpha-substituted-alpha-arylmethyl phosphonates using trichloroacetimidate C-C coupling method
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F18%3A00102481" target="_blank" >RIV/00216224:14310/18:00102481 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tet.2018.02.033" target="_blank" >http://dx.doi.org/10.1016/j.tet.2018.02.033</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tet.2018.02.033" target="_blank" >10.1016/j.tet.2018.02.033</a>
Alternative languages
Result language
angličtina
Original language name
Efficient synthesis of alpha-substituted-alpha-arylmethyl phosphonates using trichloroacetimidate C-C coupling method
Original language description
A simple convenient protocol for the synthesis of di-Et alpha,alpha-diaryl methylphosphonate derivs. 5a-f, 6b-f, 7a-f and 8a-f, di-Et alpha-alkenyl alpha-aryl methylphosphonates 9a-d and 10a-d and alpha-(oxoalkyl) alpha-aryl methylphosphonate 11a-d and 12a-d is described. Trichloroacetimidates 3a-d were treated with activated arenes, styrene, allyltrimethylsilane or silylenol ethers C-nucleophiles in the presence TMSOTf to afford the desired products in good yields and short reaction time.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Tetrahedron
ISSN
0040-4020
e-ISSN
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Volume of the periodical
74
Issue of the periodical within the volume
14
Country of publishing house
CH - SWITZERLAND
Number of pages
11
Pages from-to
1681-1691
UT code for WoS article
000428484000008
EID of the result in the Scopus database
2-s2.0-85042428758