Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F21%3A00118726" target="_blank" >RIV/00216224:14310/21:00118726 - isvavai.cz</a>
Alternative codes found
RIV/60193697:_____/19:N0000049
Result on the web
<a href="https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1679804" target="_blank" >https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1679804</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/03067319.2019.1679804" target="_blank" >10.1080/03067319.2019.1679804</a>
Alternative languages
Result language
angličtina
Original language name
Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry
Original language description
Methods useful for the extraction of alkylphenols from soil samples were assessed. A comparison is made of the four extraction techniques that are most commonly used to extract phenolic compounds from soil, such as bisphenol A, bisphenol F and alkylphenols (4-t-OP, iso-NP, 4-OP and 4-n-NP). Soxhlet extraction, ultrasonic-assisted extraction (USE), accelerated solvent extraction (ASE) and the so-called Quick, Easy, Cheap, Effective, Rugged and Safe extraction (QuEChERS) were included. Modifications of the QuEChERS technique such as original, citrate and acetate were investigated. The effects of basic purification sorbents used for QuEChERS extracts such as a primary and secondary amine (PSA), C18 endcapped sorbents and graphitised carbon black (GCB) were tested. A derivatisation step prior to the final analyses by liquid chromatography coupled to a triple quadrupole analyser operating in tandem mass spectrometry (LC-MS/MS) was performed by using dansyl chloride (DNSC). The best extraction of the monitored compounds from spiked soil was obtained using QuEChERS extraction. Recoveries of phenolic compounds using the QuEChERS technique were in the range from 67% to 114%. The lowest extraction recoveries (16-73%) were obtained using ultrasonic extraction. The QuEChERS method was successfully applied for the analysis of alkylphenols in soil samples. Instrumental limits of quantification and limits of detection ranged from 0.08 to 0.83 pg per injection and 0.02 to 0.25 pg per injection, respectively.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Environmental Analytical Chemistry
ISSN
0306-7319
e-ISSN
1029-0397
Volume of the periodical
101
Issue of the periodical within the volume
9
Country of publishing house
GB - UNITED KINGDOM
Number of pages
15
Pages from-to
1287-1301
UT code for WoS article
000492108700001
EID of the result in the Scopus database
2-s2.0-85074522266