Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60193697%3A_____%2F19%3AN0000049" target="_blank" >RIV/60193697:_____/19:N0000049 - isvavai.cz</a>

Alternative codes found

RIV/00216224:14310/21:00118726

Result on the web

<a href="https://www.tandfonline.com/doi/figure/10.1080/03067319.2019.1679804?scroll=top&needAccess=true" target="_blank" >https://www.tandfonline.com/doi/figure/10.1080/03067319.2019.1679804?scroll=top&needAccess=true</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/03067319.2019.1679804" target="_blank" >10.1080/03067319.2019.1679804</a>

Result language

angličtina

Original language name

Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry

Original language description

Methods useful for the extraction of alkylphenols from soil samples were assessed. A comparison is made of the four extraction techniques that are most commonly used to extract phenolic compounds from soil, such as bisphenol A, bisphenol F and alkylphenols (4-t-OP, iso-NP, 4-OP and 4-n-NP). Soxhlet extraction, ultrasonic-assisted extraction (USE), accelerated solvent extraction (ASE) and the socalled Quick, Easy, Cheap, Effective, Rugged and Safe extraction (QuEChERS) were included. Modifications of the QuEChERS technique such as original, citrate and acetate were investigated. The effects of basic purification sorbents used for QuEChERS extracts such as a primary and secondary amine (PSA), C18 endcapped sorbents and graphitised carbon black (GCB) were tested. A derivatisation step prior to the final analyses by liquid chromatography coupled to a triple quadrupole analyser operating in tandem mass spectrometry (LC–MS/MS) was performed by using dansyl chloride (DNSC). The best extraction of the monitored compounds from spiked soil was obtained using QuEChERS extraction. Recoveries of phenolic compounds using the QuEChERS technique were in the range from 67% to 114%. The lowest extraction recoveries (16–73%) were obtained using ultrasonic extraction. The QuEChERS method was successfully applied for the analysis of alkylphenols in soil samples. Instrumental limits of quantification and limits of detection ranged from 0.08 to 0.83 pg per injection and 0.02 to 0.25 pg per injection, respectively.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10406 - Analytical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

International Journal of Environmental Analytical Chemistry

ISSN

0306-7319

e-ISSN

1029-0397

Volume of the periodical

neuveden

Issue of the periodical within the volume

neuveden

Country of publishing house

GB - UNITED KINGDOM

Number of pages

15

Pages from-to

1-15

UT code for WoS article

000492108700001

EID of the result in the Scopus database

2-s2.0-85074522266