Structural Diversity of [M{N(SePPh2)2/Se,Se'}2,3] [M(II)=Sn, Pb, Cd, Hg, Se; M(III)=In, Sb, Bi].
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F97%3A00005902" target="_blank" >RIV/00216224:14310/97:00005902 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Structural Diversity of [M{N(SePPh2)2/Se,Se'}2,3] [M(II)=Sn, Pb, Cd, Hg, Se; M(III)=In, Sb, Bi].
Original language description
The anion [N(SePPh2)(2)](-) forms stable complexes with cations M(II, III); [M(II) = Sn, Se, Cd, Hg; M(III) = In, Sb, Bi], they exhibit a large diversity of structural arrangements around the metal centre. Tin(II) complex crystallizes dimorphically, as square planar and distorted tetragonal pyramidal, Pb(II) is also distorted tetragonal pyramidal, Cd(II) and Hg(II) are tetrahedral, but the Se(II) is square planar. The coordination geometry in the M(III) complexes can be described as a distorted octahedron. The structural situation around the Sb(III) and Bi(III) suggests a stereochemically non-active electron lone pair.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
—
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
1997
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Phosphorus, Sulfur Silicon Rel. Elem.
ISSN
1042-6507
e-ISSN
—
Volume of the periodical
1997
Issue of the periodical within the volume
124
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
347-354
UT code for WoS article
—
EID of the result in the Scopus database
—