Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39881463" target="_blank" >RIV/00216275:25310/10:39881463 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X
Original language description
It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped - trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a psí-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GP203%2F07%2FP094" target="_blank" >GP203/07/P094: Organoantimony(III) and organobismuth(III) compounds containing O,C,O chelating ligands</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
695
Issue of the periodical within the volume
3
Country of publishing house
CH - SWITZERLAND
Number of pages
6
Pages from-to
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UT code for WoS article
000273782000012
EID of the result in the Scopus database
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