A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14330%2F06%3A00015666" target="_blank" >RIV/00216224:14330/06:00015666 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].

Original language description

Several salts of bis(chlorosulfonyl)imide HN(SO2Cl)2 (1), namely two solvates of its potassium salt, KN(SO2Cl)2 1/2 CH3CN (1K1), KN(SO2Cl)2 1/6 CH2Cl2 (1K2), and tetrachlorophosphonium salt, [PCl4][N(SO2Cl)2] (2), were prepared and structurally characterized. The reaction of HN(SO2Cl)2 with Me3N gives the [N(SO2Cl)2]- salt of a novel cation, [N(SO2NMe3)2]+ .This cation is analogous to the [HC(SO2NMe3)2]+ cation but, in contrast to the latter, it is fairly stable to hydrolysis. The salt [N(SO2NMe3)2]+ [N(SO2Cl)2]- (3) can be converted into salts of other anions by its treatment with diluted aqueous solutions of the respective acids, and thus NO3-, Cl-.H2O, SeO32-, CH3COO-, HSO4-, (COO)22- salts were prepared. Treatment of 3 with concentrated HNO3 gave the [N(SO2NMe3)2]+ [O2NO-H-ONO2]- salt, and the addition of an HCl acidified FeCl3 aqueous solution yielded the FeCl4- salt. Methanolysis resulted in the formation of MeOSO3- and [MeOSO2NSO2OMe]- salts. All salts have been characterized by

Czech name

Nový kation [N(SO2NMe3)2]+, jeho piprava a struktura. Dichlorid imidobis(sirové) kyseliny HN(SO2Cl)2. ást 1. Krystalové strktury KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 a [PCl4][N(SO2Cl)2].

Czech description

V publikaci jsou uvedeny a prehlednym zpusobem shrnuty vysledky studia reaktivity dichloridu imidobis(sirove) kyseliny a jeho derivát. Souasti prace je rovnez charakterizace produktu studovanych reakcí vetn rtg. strukturní analýzy.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

—

Project

<a href="/en/project/GP203%2F05%2FP104" target="_blank" >GP203/05/P104: Study of the reactivity of silyl-derivatives of linear diphosphazenes with halides - preparation of new inorg. heterocyclic comp. and their structure</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

INORGANIC CHEMISTRY

ISSN

0020-1669

e-ISSN

—

Volume of the periodical

9/2006

Issue of the periodical within the volume

45

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

6

Pages from-to

3695-3700

UT code for WoS article

—

EID of the result in the Scopus database

—