Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F12%3A00057643" target="_blank" >RIV/00216224:14740/12:00057643 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2012.08.056" target="_blank" >http://dx.doi.org/10.1016/j.poly.2012.08.056</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2012.08.056" target="_blank" >10.1016/j.poly.2012.08.056</a>

Result language
angličtina
Original language name
Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand
Original language description
Architectures of coordination polymers resulting from the reaction of diphenylphosphorylvaleric acid (1) with Pr(NO3)3.6H2O in the presence of a base can be controlled by the solvent. While in methanolic solution a two-dimensional network Pr2(1?H)3(NO3)3(1m) with a 1:1.5 metal-to-ligand ratio was formed, the aqueous media induced the formation of a three-dimensional framework Pr(1?H)2(NO3) (1w) with a 1:2 metal-to-ligand ratio. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, ESI-TOF mass spectrometry, and thermal analysis TG/DSC techniques.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)