Synthesis and characterization of a cobalt(II) complex with(E)-ń-(2-Hydroxy-3-Methoxybenzylidene)isonicotinohydrazide and (E)-ń-(2-Hydroxy-3-Methoxybenzylidene)isonicotinohydrazidanium nitrate as a by-product
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00455928" target="_blank" >RIV/68378271:_____/15:00455928 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/15533174.2013.862827" target="_blank" >http://dx.doi.org/10.1080/15533174.2013.862827</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/15533174.2013.862827" target="_blank" >10.1080/15533174.2013.862827</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and characterization of a cobalt(II) complex with(E)-ń-(2-Hydroxy-3-Methoxybenzylidene)isonicotinohydrazide and (E)-ń-(2-Hydroxy-3-Methoxybenzylidene)isonicotinohydrazidanium nitrate as a by-product
Original language description
A Schiff base ligand HL was synthesized from the reaction of isonicotinic acid hydrazide with 3-methoxysalicylaldehyde. The reaction of HL with Co(NO3)2 .6H2O in methanol gave dark red crystals of [Co(HL)2](NO3)2.3H2O and colorless crystals (HLH)(NO3). In coordination to metal, Schiff base ligand was protonated via hetrocyclic nitrogen atom of the pyridine ring and deprotonated on the phenolic OH group. The extensive O?H...O and N?H...O hydrogen bonds form an infinite one-dimensional chain in the complex.n
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
ISSN
1553-3174
e-ISSN
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Volume of the periodical
45
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
1506-1512
UT code for WoS article
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EID of the result in the Scopus database
2-s2.0-84930197938