Synthesis, characterization, crystal structure determination, thermal study and catalytic activity of a new oxidovanadium Schiff base complex

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00434955" target="_blank" >RIV/68378271:_____/14:00434955 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2014.07.073" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2014.07.073</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2014.07.073" target="_blank" >10.1016/j.molstruc.2014.07.073</a>

Result language
angličtina
Original language name
Synthesis, characterization, crystal structure determination, thermal study and catalytic activity of a new oxidovanadium Schiff base complex
Original language description
A new bidentate ON Schiff base ligand of HL (HL = 5-nitro-2-hydroxybenzyl-2-furylmethyl) imine), was synthesized by simple condensation reaction of 5-nitro-2-hydroxybenzaldehyde and 2-furfurylamine. Then by reaction of a methanolic solutions of the HL and VO(acac)2 in the ratio of 2:1, a new oxidovana- dium(IV) Schiff base complex of VOL2 was synthesized. The Schiff base ligand and its vanadyl Schiff base complex were characterized by FT-IR, UV-vis spectra and CHN analysis. Single crystals suitable forX-ray analysis were obtained in DMSO as a VOL2(DMSO) complex. The crystal structure of the VOL2 (DMSO) was determined by the single-crystal X-ray analysis. Decomposition of the vanadyl Schiff base complex (VOL2) in air at 660 deg C resulted in the formation of the V2O5 nano particles with the average size of 52 nm.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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