Synthesis, characterization, crystal structure determination, catalytic activity and thermal study of a new oxidovanadium(IV) Schiff base complex: production of V2O5 nano-particles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00434839" target="_blank" >RIV/68378271:_____/14:00434839 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s13738-013-0361-y" target="_blank" >http://dx.doi.org/10.1007/s13738-013-0361-y</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s13738-013-0361-y" target="_blank" >10.1007/s13738-013-0361-y</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, characterization, crystal structure determination, catalytic activity and thermal study of a new oxidovanadium(IV) Schiff base complex: production of V2O5 nano-particles
Original language description
A new oxidovanadium(IV) Schiff base complex, VOL2 (1), containing furfuryl pendant group was synthesized by the reaction of the related bidentate O,N-type Schiff base ligand and VO(acac)2. The Schiff base ligand and its vanadyl complex were characterizedby 1H-NMR and FT-IR spectra and elemental analysis. The crystal structure of 1 was also determined the single-crystal X-ray analysis. The catalytic activity of the vanadyl Schiff base complex was elucidated in the epoxidation of cyclooctene as a model substrate. In addition, the vanadyl Schiff base complex (1) was thermally decomposed in air at 6 60 deg C and the XRD pattern of the obtained solid showed the formation of the V2O5 nanoparticles with the average size of 52 nm.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the Iranian Chemical Society
ISSN
1735-207X
e-ISSN
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Volume of the periodical
11
Issue of the periodical within the volume
4
Country of publishing house
IR - IRAN, ISLAMIC REPUBLIC OF
Number of pages
10
Pages from-to
953-962
UT code for WoS article
000337597000002
EID of the result in the Scopus database
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