Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F14%3A00076814" target="_blank" >RIV/00216224:14740/14:00076814 - isvavai.cz</a>
Alternative codes found
RIV/68081707:_____/14:00429108 RIV/61388955:_____/14:00429108
Result on the web
<a href="http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract" target="_blank" >http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4cc01992j" target="_blank" >10.1039/c4cc01992j</a>

Result language
angličtina
Original language name
Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
Original language description
High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of theproduct gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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