Two new thiophosphoramide structures: N,N ',N ''-tricyclohexylphosphorothioic triamide and O,O '-diethyl (2-phenylhydrazin-1-yl)thiophosphonate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F14%3A00079169" target="_blank" >RIV/00216224:14740/14:00079169 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1107/S2053229614022608" target="_blank" >http://dx.doi.org/10.1107/S2053229614022608</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S2053229614022608" target="_blank" >10.1107/S2053229614022608</a>
Alternative languages
Result language
angličtina
Original language name
Two new thiophosphoramide structures: N,N ',N ''-tricyclohexylphosphorothioic triamide and O,O '-diethyl (2-phenylhydrazin-1-yl)thiophosphonate
Original language description
The compound N,N',N"-tricyclohexylphosphorothioic triamide, C18H36N3PS or P(S)[NHC6H11](3), (I), crystallizes in the space group Pnma with the molecule lying across a mirror plane; one N atom lies on the mirror plane, whereas the bond-angle sum at the other N atom has a deviation of some 8 degrees from the ideal value of 360 degrees for a planar configuration. The orientation of the atoms attached to this nonplanar N atom corresponds to an anti orientation of the corresponding lone electron pair (LEP) with respect to the P=S group. The P=S bond length of 1.9785 (6) angstrom is within the expected range for compounds with a P(S)[N](3) skeleton; however, it is in the region of the longest bond lengths found for analogous structures. This may be due to the involvement of the P=S group in N-H center dot center dot center dot S=P hydrogen bonds.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
ISSN
0108-2701
e-ISSN
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Volume of the periodical
70
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
1147-1152
UT code for WoS article
000345959700013
EID of the result in the Scopus database
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