Two new thiophosphoramide structures: N,N',N''-tricyclohexylphosphorothioictriamide and O,O'-diethyl(2-phenylhydrazin-1-yl)thiophosphonate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00440549" target="_blank" >RIV/68378271:_____/14:00440549 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1107/S2053229614022608" target="_blank" >http://dx.doi.org/10.1107/S2053229614022608</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S2053229614022608" target="_blank" >10.1107/S2053229614022608</a>
Alternative languages
Result language
angličtina
Original language name
Two new thiophosphoramide structures: N,N',N''-tricyclohexylphosphorothioictriamide and O,O'-diethyl(2-phenylhydrazin-1-yl)thiophosphonate
Original language description
The compound N,N',N''-tricyclohexylphosphorothioic triamide, C18H36N3PS or P(S)[NHC6H11]3, (I), crystallizes in the space group Pnma with the molecule lying across a mirror plane; one N atom lies on the mirror plane, whereas the bondangle sum at the other N atom has a deviation of some 8° from the ideal value of 360° for a planar configuration. The orientation of the atoms attached to this nonplanar N atom corresponds to an anti orientation of the corresponding lone electron pair (LEP) with respect to the P S group. The P S bond length of 1.9785 (6) A ° is within the expected range for compounds with a P(S)[N]3 skeleton; however, it is in the region of the longest bond lengths found for analogous structures. This may be due to the involvement of the PSgroup in N?H...S=P hydrogen bonds.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica. Section C: Structural Chemistry
ISSN
2053-2296
e-ISSN
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Volume of the periodical
70
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
1147-1152
UT code for WoS article
000345959700013
EID of the result in the Scopus database
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