A new phosphorothioic triamide structure: P(S)[NHCH2C6H5]3./sub
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00451337" target="_blank" >RIV/68378271:_____/15:00451337 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1107/S2053229615004453" target="_blank" >http://dx.doi.org/10.1107/S2053229615004453</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S2053229615004453" target="_blank" >10.1107/S2053229615004453</a>
Alternative languages
Result language
angličtina
Original language name
A new phosphorothioic triamide structure: P(S)[NHCH2C6H5]3./sub
Original language description
The structure of N,N0,N00-tribenzylphosphorothioic triamide, C21H24N3PS, (I), and analysis of the bond-angle sums at the N atoms for this compound, and for 74 structures with a P(S)[N]3 skeleton and the N atom in a three-coordinate geometry found in theCambridge Structural Database [CSD; Groom & Allen (2014). Angew. Chem. Int. Ed. 53, 662?671], are reported. For (I), the bond-angle sum at one of the N atoms [359 (1)] shows a nearly planar configuration, while the other two show a nonplanar geometry with bond-angle sums of 342 (1) and 347 (1). The location of the atoms attached to the nonplanar N atoms suggests an anti orientation of the corresponding lone electron pairs (LEPs) on these N atoms with respect to the P S group. For 74 structures with a P(S)[N]3 skeleton and with the N atom in a three-coordinate geometry, the bond-angle sums at the N atoms were found to be in the range 293?360.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica. Section C: Structural Chemistry
ISSN
2053-2296
e-ISSN
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Volume of the periodical
71
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
338-343
UT code for WoS article
000352159200019
EID of the result in the Scopus database
2-s2.0-84926453444