Structure and Base Catalysed Cyclization of Methyl (2,6-Disubstituted-4-nitrophenylsulphanyl)ethanoates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F03%3A00000495" target="_blank" >RIV/00216275:25310/03:00000495 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Structure and Base Catalysed Cyclization of Methyl (2,6-Disubstituted-4-nitrophenylsulphanyl)ethanoates
Original language description
The conformation of side chain #SCH2COOCH3 in title compounds in crystal agrees with the reactivity of these compounds in base-catalysed ring closure in solution. In the 2,4-dinitro derivative, the side chain is oriented towards the unsubstituted ortho-position of benzene ring, in the case of the 2-methoxycarbonyl derivative towards this substituent.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F01%2F0227" target="_blank" >GA203/01/0227: Intramolecular nucleophilic substitution. Extraordinary steric acceleration in a reaction of carbanion with electrophilic centre</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
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Volume of the periodical
Neuveden
Issue of the periodical within the volume
658
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
33-42
UT code for WoS article
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EID of the result in the Scopus database
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