An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F04%3A00001635" target="_blank" >RIV/00216275:25310/04:00001635 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
An experiment and theoretical study of the Cp2VO2CO: use (CO32-)-C-13 for structure investigation of d(1)-metallocene complexes
Original language description
EPR study has shown that the anticancer agent vanadocene dichloride (Cp2VCl2) interacts with carbonate contained in physiological solutions. Chelate complex Cp2VO2CO (A(iso)(V-51) = 175.1 MHz, g(iso) = 1.9861) is the only paramagnetic species formed inthe range about the physiological pH (5.5-11.0). The superhyperfine coupling (a(iso)(C-13) = 24.1 MHz) was evidenced at measurements using C-13 labelled carbonate. The structure of carbonate complex was validated by comparison of observed and theoretical calculated HFC tensors (at the density functional level of theory).
Czech name
Experimentální a teoretické studium Cp2VO2CO: použití (CO32-)-C-13 zkoumání struktury d(1)-metalocenových komplexů
Czech description
Experimentální a teoretické studium Cp2VO2CO: použití (CO32-)-C-13 zkoumání struktury d(1)-metalocenových komplexů
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Magnetic Resonance in Chemistry
ISSN
0749-1581
e-ISSN
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Volume of the periodical
42
Issue of the periodical within the volume
10
Country of publishing house
GB - UNITED KINGDOM
Number of pages
5
Pages from-to
870-874
UT code for WoS article
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EID of the result in the Scopus database
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