Molecular structure study of a heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin complex of cholesterol
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F20%3A00121452" target="_blank" >RIV/00216224:14740/20:00121452 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0039128X19302454?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0039128X19302454?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.steroids.2019.108555" target="_blank" >10.1016/j.steroids.2019.108555</a>
Alternative languages
Result language
angličtina
Original language name
Molecular structure study of a heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin complex of cholesterol
Original language description
Heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin (2) and cholesterol form a water-soluble complex 3. We performed several NMR studies, particularly H-1, C-13, 2D NOESY and DOSY, at various temperatures on 500 and 950 MHz instruments. We discovered that the complex 3 is unstable above 57 degrees C in heavy water, while it is kinetically stable enough to be studied by NMR in detail at 1 degrees C. We demonstrated the formation of a face-to-face 2:1 complex with a binding constant of approximately 2.2 x 10(6) M-2.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10608 - Biochemistry and molecular biology
Result continuities
Project
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Continuities
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Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Steroids
ISSN
0039-128X
e-ISSN
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Volume of the periodical
155
Issue of the periodical within the volume
MAR
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
108555
UT code for WoS article
000517349300010
EID of the result in the Scopus database
2-s2.0-85077653572