Syntheses and structures of N,C,N-stabilized antimony chalcogenides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911698" target="_blank" >RIV/00216275:25310/17:39911698 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2017.01.007" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2017.01.007</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2017.01.007" target="_blank" >10.1016/j.jorganchem.2017.01.007</a>
Alternative languages
Result language
angličtina
Original language name
Syntheses and structures of N,C,N-stabilized antimony chalcogenides
Original language description
The oxidation reactions of ArSb [Ar = 2,6-( HC=N-t- Bu)(2)C6H3] with S-8, grey Se and Te as well as E2Ph2 (E== S, Se, Te) are demonstrated. The reactions of ArSb with elemental sulfur and selenium occurred at elevated temperatures and yielded ArSbE (E== S, 1; Se 2), whereas the reactions with E2Ph2 proceeded at room temperature with subsequent formation of the corresponding insertion complexes ArSb(EPh) 2 (E==S 3; Se 4). In addition, ArSb(TePh)(2) (5) was formed at very low temperature and showed a temperature-dependent reversible equilibrium with ArSb and Te2Ph2 between -80 degrees C and 20 degrees C. The formation and structure of compounds 1-4, which were isolated in good yields, are assigned through multinuclear NMR (H-1, C-13, Se-77), IR spectroscopy and microanalyses data. In addition, the molecular structures of 2-4 are further confirmed by single crystal X-ray diffraction studies.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA15-06609S" target="_blank" >GA15-06609S: Stibinidenes and Bismuthinidenes – A New Class of Ligands for Transition Metals</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
845
Issue of the periodical within the volume
September
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
38-43
UT code for WoS article
000405773500007
EID of the result in the Scopus database
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