Intramolecularly Coordinated Stannanechalcogenones: X-ray Structure of [2,6-(Me2NCH2)2C6H3](Ph)Sn=Te

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892015" target="_blank" >RIV/00216275:25310/11:39892015 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/11:43891414
Result on the web
<a href="http://dx.doi.org/10.1021/om200751g" target="_blank" >http://dx.doi.org/10.1021/om200751g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om200751g" target="_blank" >10.1021/om200751g</a>

Result language
angličtina
Original language name
Intramolecularly Coordinated Stannanechalcogenones: X-ray Structure of [2,6-(Me2NCH2)2C6H3](Ph)Sn=Te
Original language description
The treatment of an intramolecularly coordinated organotin(IV) dichloride, [2,6-(Me2NCH2)2C6H3](Ph)SnCl2 (1), with Li2E (E = S, Se, Te) afforded thermally stable dimeric diarylstannanethione [{2,6-(Me2NCH2)2C6H3}(Ph)Sn(mu-S)]2 (2) and monomeric diarylstannaneselone and -tellurone [{2,6-(Me2NCH2)2C6H3}(Ph)Sn=E] (E = Se (3), Te (4)). Compounds 2?4 were characterized by means of elemental analyses and 1H, 13C, 77Se, 119Sn, and 125Te NMR spectroscopy. The molecular structures of 2 and 4 were determined by single-crystal X-ray diffraction analysis. Solution NMR studies revealed dependence of the structure of compounds 2 and 3 on the solvent (C6D6 or CDCl3). In addition, the synthesis of dimeric stannanetellurone [{2,6-(Me2NCH2)2C6H3}(Bu)Sn(mu-Te)]2 (5) showed an influence of the organic group R (R = Bu or Ph) on the structure of diorganotin(IV) tellurides 4 and 5.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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