Reactivity of Organotin(I) Dimers RSnSnR (R = 2,6-(Me2NCH2)2C6H3, 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2) with Diaryl Dichalcogenides, ArEEAr (E = S, Se, Te; Ar = Ph, 2-C5H4N): Control of Secondary Sn???Sn Interactions by Intramolecular Coordination and Identity of the Aryl Chalcogenate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896813" target="_blank" >RIV/00216275:25310/13:39896813 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om400694z" target="_blank" >http://dx.doi.org/10.1021/om400694z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om400694z" target="_blank" >10.1021/om400694z</a>

Result language
angličtina
Original language name
Reactivity of Organotin(I) Dimers RSnSnR (R = 2,6-(Me2NCH2)2C6H3, 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2) with Diaryl Dichalcogenides, ArEEAr (E = S, Se, Te; Ar = Ph, 2-C5H4N): Control of Secondary Sn???Sn Interactions by Intramolecular Coordination and Identity of the Aryl Chalcogenate
Original language description
The reactions of the in situ prepared organotin(I) compounds RSnSnR with diary! dichalcogenides ArEEAr provided, depending on the ratio of the reactants, the intramolecularly coordinated heteroleptic organotin(II) chalcogenoarylates RSnEAr (1, R = 2,6-(Me2NCH2)(2)C6H3, -E = S, Ar = Ph; 2, R = 2,6-(Me2NCH2)(2)C6H3, E = Se, Ar = Ph; 3, R = 2,6(Me2NCH2)(2)C6H3, E Te, Ar = Ph; 6, R = 4-t-Bu-2,6-{P(O)(O-i-ET)z}(2)C6H2, E = Se, Ar = Ph; 7, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)(2)}(2)C6H2, E = Te, Ar = Ph; 8, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)(2)}(2)C6H2, E = Se, Ar = 2-C5H4N) and the corresponding organotin(IV) compounds RSn(EAr)(3) (4, R = 2,6-(Me2NCH2)(2)C6H3, E = S, Ar = Ph; 5, R = 2,6-(Me2NCH2)(2)C6H3, E = Se, Ar = Ph; 10, R = 4-t-Bu-2,6-{P(O)(O-i-PO2}(2)C6H2, E = S, Ar = 2-C5H4N), respectively. Compound 1O undergoes a thermally initiated cyclization reaction to give the benzoxaphosphastannole derivative {1(P),3(Sn)-Sn(S-Py)2-OP(O)(O-i-Pr)-6-t-Bu-4-P(O)(Oi-Pr)2}C6H2 (11). The compounds were characteriz
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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