Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)zirconium(IV)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F05%3A00002705" target="_blank" >RIV/00216275:25310/05:00002705 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/05:00008458 RIV/00216208:11310/05:8458
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)zirconium(IV)
Original language description
The title compound, [ZrBr2(C13H24)], contains a pseudotetrahedral ZrIV centre involving two eta-5-bonded cyclopentadienyl rings [Zr-Cg = 2.1843 (12) A° ; Cg is the centroid of acyclopentadienyl ring] and two Br atoms [Zr-Br = 2.5828 (5) and 2.5879 (6) A°]. The angle Cg1-Zr-Cg2 is constrained to a value of 116.80 (5)DEG due to the presence of a short interannular 2,2-propylidene bridge. The Zr and Br atoms lie on a crystallographic mirror plane, which bisects the organic ligand.
Czech name
Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)zirconium(IV)
Czech description
The title compound, [ZrBr2(C13H24)], contains a pseudotetrahedral ZrIV centre involving two eta-5-bonded cyclopentadienyl rings [Zr-Cg = 2.1843 (12) A° ; Cg is the centroid of acyclopentadienyl ring] and two Br atoms [Zr-Br = 2.5828 (5) and 2.5879 (6) A°]. The angle Cg1-Zr-Cg2 is constrained to a value of 116.80 (5)DEG due to the presence of a short interannular 2,2-propylidene bridge. The Zr and Br atoms lie on a crystallographic mirror plane, which bisects the organic ligand.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
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Issue of the periodical within the volume
61
Country of publishing house
GB - UNITED KINGDOM
Number of pages
2
Pages from-to
"m2424"-"m2425"
UT code for WoS article
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EID of the result in the Scopus database
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