Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006414" target="_blank" >RIV/00216275:25310/07:00006414 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)
Original language description
In the molecule of the title compound, C13H14Br2Ti, the Ti(IV) centre is in a distorted tetrahedral environment involving two eta5-bonded cyclopenta dienyl rings of (C13H14)2- ligand [Ti-Cg = 2.045(2) A; Cg is the centroid of cyclopentadienyl ring] and two Br atoms [Ti-Br = 2.5115(7) A]. The constraining of the Cg-Ti-Cg angle to a value of 121.32(9)° is caused by the presence of the short 2,2-propylidene bridge between the two cyclopenta- dienyl rings. The Ti and central C atoms are located on a crystallographic C2 axis.
Czech name
Dibromo(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)
Czech description
In the molecule of the title compound, C13H14Br2Ti, the Ti(IV) centre is in a distorted tetrahedral environment involving two eta5-bonded cyclopenta dienyl rings of (C13H14)2- ligand [Ti-Cg = 2.045(2) A; Cg is the centroid of cyclopentadienyl ring] and two Br atoms [Ti-Br = 2.5115(7) A]. The constraining of the Cg-Ti-Cg angle to a value of 121.32(9)° is caused by the presence of the short 2,2-propylidene bridge between the two cyclopenta- dienyl rings. The Ti and central C atoms are located on a crystallographic C2 axis.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
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Issue of the periodical within the volume
63
Country of publishing house
DK - DENMARK
Number of pages
1
Pages from-to
"m2699"
UT code for WoS article
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EID of the result in the Scopus database
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