C, N and N, C, N-chelated Organotin (IV) Fluorides

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00005940" target="_blank" >RIV/00216275:25310/07:00005940 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

C, N and N, C, N-chelated Organotin (IV) Fluorides

Original language description

One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms.

Czech name

C, N and N, C, N-chelated Organotin (IV) Fluorides

Czech description

One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms.

Type

C - Chapter in a specialist book

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Book/collection name

Fluorine Chemistry Research Advances

ISBN

1-60021-730-3

Number of pages of the result

31

Pages from-to

281-312

Number of pages of the book

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Publisher name

Nova Science Publishers

Place of publication

NY, USA

UT code for WoS chapter

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