C,N-chelated Organotin(IV) Trifluoroacetates. Instability of the Mono- and Diorganotin(IV) Derivatives

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39882366" target="_blank" >RIV/00216275:25310/11:39882366 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2010.09.050" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2010.09.050</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2010.09.050" target="_blank" >10.1016/j.jorganchem.2010.09.050</a>

Result language
angličtina
Original language name
C,N-chelated Organotin(IV) Trifluoroacetates. Instability of the Mono- and Diorganotin(IV) Derivatives
Original language description
The C,N-chelated tri-, di- and monoorganotin(IV) halides react with equimolar amounts of CF 3COOAg to give corresponding C,N-chelated organotin(IV) trifluoroacetates. The set of prepared tri-, di- and monoorganotin(IV) trifluoroacetates bearing the L CNligand (where L CN is 2-(N,N-dimethylaminomethyl)phenyl-) was structurally characterized by X-ray diffraction analyses, multinuclear NMR and IR spectroscopy. In the case of triorganotin(IV) trifluoroacetates and (L CN) 2Sn(OC(O)CF 3) 2, no tendency to form hydrolytic products, or instability towards the moisture was observed. L CNRSn(OC(O)CF 3) 2 (where R is n-Bu or Ph) and L CNSn(OC(O)CF 3) 3 forms upon crystallization from THF in the air mainly dinuclear complexes in which the two tin atoms are interconnected either by hydroxo-bridges or by an oxo-bridge and/or by a bridging trifluoroacetate(s).
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)