Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006086" target="_blank" >RIV/00216275:25310/07:00006086 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands

Original language description

EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (|aiso(13C)| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra.

Czech name

Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands

Czech description

EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (|aiso(13C)| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Magnetic Resonance in Chemistry

ISSN

0749-1581

e-ISSN

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Volume of the periodical

45

Issue of the periodical within the volume

45

Country of publishing house

GB - UNITED KINGDOM

Number of pages

5

Pages from-to

508-512

UT code for WoS article

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EID of the result in the Scopus database

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