Crystallography of 2,2',4,4',6,6'-hexanitro-1,1'-biphenyl and its relation to initiation reactivity
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006323" target="_blank" >RIV/00216275:25310/07:00006323 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/08:00007945
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Crystallography of 2,2',4,4',6,6'-hexanitro-1,1'-biphenyl and its relation to initiation reactivity
Original language description
X-Ray crystallographic study of 2,2´,4,4´,6,6´-hexanitro-1,1´-biphenyl (HNBP, C12H4N6O12, Mr = 424.21) has been carried out. A possibility of intermolecular hydrogen bonds was indicated and atypically short distances between oxygen atoms of nitro groupsin the 2,6-positions of one molecule and nitro groups in the 4-position of adjacent molecules were found. These interactions might be a reason of the primary reaction of nitro group in the position 4(4´), compared to nitro groups in positions 2,6(2´,6´),in the HNBP molecule during its initiation. In this respect, HNBP differs from the other members of polynitro polyphenylene series containing trinitrophenyl building blocks in their molecules.
Czech name
Krystalografie 2,2',4,4',6,6'-hexanitro-1,1'-biphenylu a její vztah k jeho iniciační reaktivitě
Czech description
Roentgenografická studie of 2,2´,4,4´,6,6´-hexanitro-1,1´-biphenylu (HNBP, C12H4N6O12, Mr = 424.21) byla realizována. Byla indikována možnost existence intermolekulární vodíkové vazby a atypicky krátké vzdálenosti mezi kyslíkovými atomy nitoskupin v 2,6-polohách jedné molekuly a nitroskupin v poloze 4 přilehlé molekuly. Tyto interakce mohou být příčinou primárních reakcí nitroskupiny v poloze 4(4´),v porovnání s nitroskupinami v polohách 2,6(2´,6´), v molekule HNBP během její iniciace. V tomto smyslu seHNBP liší od jiných členů polynitro polyfenylenů, obsahujících v molekule trinitrofenylové stavební jednotky.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry of Materials
ISSN
0897-4756
e-ISSN
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Volume of the periodical
N
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
12
Pages from-to
123-137
UT code for WoS article
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EID of the result in the Scopus database
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