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Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008296" target="_blank" >RIV/00216275:25310/09:00008296 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid

  • Original language description

    1H, 13C NMR and MS spectra of the 2:1 cobalt(III) complexes derived the azo coupling products of 2-aminophenol or 2-aminobenzoic acid with the citrazinic acid were measured and analysed. It was found that the cobalt atom is six-coordinated being bound totwo oxygens (one from primary and one from secondary component) and the nitrogen of 2-aminophenol or 2-aminobenzoic acid. Molar magnetic susceptibility data proved the presence of Co(III). Diazotisation of 2-aminophenol or 2-aminobenzoic acid and subsequent coupling reaction with citrazinic acid and complexation of the formed azo product proceeded on standard way.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Cimmunications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    74

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database