Systematic Method for the Incorporation of the {(eta(6)-Arene)Fe} Fragment into Carborane Cages via [(eta(6)-Arene)Fe](2+) Dications. A Series of [3-(eta(6)-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(eta(6)-Arene)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008337" target="_blank" >RIV/00216275:25310/09:00008337 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/09:00340428

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Systematic Method for the Incorporation of the {(eta(6)-Arene)Fe} Fragment into Carborane Cages via [(eta(6)-Arene)Fe](2+) Dications. A Series of [3-(eta(6)-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(eta(6)-Arene)

Original language description

Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry

ISSN

0020-1669

e-ISSN

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Volume of the periodical

48

Issue of the periodical within the volume

23

Country of publishing house

US - UNITED STATES

Number of pages

3

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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