Thermal isomerization of eta(6)-arene ferradicarbolllides. Experimental proof for isolobal relation between (eta(6)-arene)Fe and (eta(5)-cyclopentadienyl)Co cluster units.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892417" target="_blank" >RIV/00216275:25310/11:39892417 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c1dt10367a" target="_blank" >http://dx.doi.org/10.1039/c1dt10367a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c1dt10367a" target="_blank" >10.1039/c1dt10367a</a>

Result language
angličtina
Original language name
Thermal isomerization of eta(6)-arene ferradicarbolllides. Experimental proof for isolobal relation between (eta(6)-arene)Fe and (eta(5)-cyclopentadienyl)Co cluster units.
Original language description
The heating of selected [1-(eta(6)-arene)-closo-1,2,3-FeC(2)B(9)H(11)] complexes resulted in the thermal rearrangement and isolation of the corresponding 1,2,4-, 1,2,7-, and 1,2,8-cage isomers. Demonstrated here is a similar rearrangement and the NMR behaviour for isostructural [1-(eta(5)-cyclopentadienyl)-closo-1,2,3-CoC(2)B(9)H(11)] compounds.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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