Thermal isomerization of eta(6)-arene ferradicarbolllides. Experimental proof for isolobal relation between (eta(6)-arene)Fe and (eta(5)-cyclopentadienyl)Co cluster units

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F11%3A00372296" target="_blank" >RIV/61388980:_____/11:00372296 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1039/c1dt10367a" target="_blank" >http://dx.doi.org/10.1039/c1dt10367a</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c1dt10367a" target="_blank" >10.1039/c1dt10367a</a>

Result language

angličtina

Original language name

Thermal isomerization of eta(6)-arene ferradicarbolllides. Experimental proof for isolobal relation between (eta(6)-arene)Fe and (eta(5)-cyclopentadienyl)Co cluster units

Original language description

The heating of selected [1-(eta(6)-arene)-closo-1,2,3-FeC(2)B(9)H(11)] complexes resulted in the thermal rearrangement and isolation of the corresponding 1,2,4-, 1,2,7-, and 1,2,8-cage isomers. Demonstrated here is a similar rearrangement and the NMR behaviour for isostructural [1-(eta(5)-cyclopentadienyl)-closo-1,2,3-CoC(2)B(9)H(11)] compounds

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Volume of the periodical

40

Issue of the periodical within the volume

25

Country of publishing house

GB - UNITED KINGDOM

Number of pages

3

Pages from-to

6623-6625

UT code for WoS article

000291663600005

EID of the result in the Scopus database

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