[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39882028" target="_blank" >RIV/00216275:25310/10:39882028 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,
Original language description
The molecular structures of the intramolecularly coordinated tungstenpentacarbonyl organostannylene complexes 2,6-(Me2NCH2)2C6H3(Cl)SnW(CO)5 and [2,6-(Me2NCH2)2C6H3(H2O)SnW(CO)5]+(CB11H12)- are reported. The latter compound is an aqua complex in which the water molecule replaces one of the two N?Sn coordination sites. The coordination of the water molecule is accompanied by proton transfer to the nitrogen atom. DFT calculations reveal this to be the thermodynamically most-stable structure.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
neuveden
Issue of the periodical within the volume
6
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
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UT code for WoS article
000275240500009
EID of the result in the Scopus database
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