Tetrylenes Chelated by Hybrid Amido-Amino Ligand: Derivatives of 2-[(N,N-Dimethylamino)methyl]aniline

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892393" target="_blank" >RIV/00216275:25310/11:39892393 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ic2011056" target="_blank" >http://dx.doi.org/10.1021/ic2011056</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic2011056" target="_blank" >10.1021/ic2011056</a>

Result language
angličtina
Original language name
Tetrylenes Chelated by Hybrid Amido-Amino Ligand: Derivatives of 2-[(N,N-Dimethylamino)methyl]aniline
Original language description
Reaction of 2-[(dimethylamino)methyl]aniline with butyllithium, followed by conversion with triinethylsilyl, triphenylsilyl, triphenylgermyl, trimethylstannyl, or tri-n-butyl-stannyl chloride, gives the corresponding substituted aniline. These compoundswere further deprotonated by butyllithium and reacted with germanium, tin, and lead dichlorides, respectively, in both stoichiometric ratios 2:1 and 1:1, providing the target homo- ([2-(Me(2)NCH(2))C(6)H(4)(YR(3))N](2)M) and heteroleptic ([2-(Me(2)NCH(2))C(6)H(4) (YR(3))N]MCl) germylenes and stannylenes, where M = Ge, Sn, Y = Si, Ge, and R = Me, Ph. Unlike all of these cases, the heteroleptic plumbylene can only be obtained with this reaction when the amide is substituted by a trimethylsilyl moiety. Anilines substituted by trimethyltin or tri-n-butyltin moieties gave transmetalation products after the second deprotonation by butyllithium. The trimethyltin-substituted stannylenes could likewise not be obtained by hexamethyldisilazane eli
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GPP207%2F10%2FP092" target="_blank" >GPP207/10/P092: Activation of Small Molecules and Unsaturaturated Systems by Tin Compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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