Self-assembled hydrogen-bonded coordination networks in two copper(II) carboxylates with 4-pyridylmethanol

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892426" target="_blank" >RIV/00216275:25310/11:39892426 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.2478/s11532-011-0023-9" target="_blank" >http://dx.doi.org/10.2478/s11532-011-0023-9</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.2478/s11532-011-0023-9" target="_blank" >10.2478/s11532-011-0023-9</a>

Result language
angličtina
Original language name
Self-assembled hydrogen-bonded coordination networks in two copper(II) carboxylates with 4-pyridylmethanol
Original language description
The crystal and molecular structure of [Cu(nif)(2)(4-PM)(2)]center dot CH(3)OH (1) and [Cu(2-Clbz)(2)(4-PM)(2)(H(2)O)] (2), (where nif = niflumate anion, 2-Clbz = 2-chlorobenzoate anion and 4-PM is the 4-pyridylmethanol), have been determinated by X-raycrystallography. The Cu(2+) cation in (1), is coordinated by two pairs of oxygen atoms from asymmetric bidentate niflumate anions and by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands in trans position forming an extremely elongated bipyramid. The Cu(2+) cation in (2), is coordinated by a pair of oxygen atoms from monodentate 2-chlorobenzoate anions, further by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands and finally by a water oxygen atom forming a tetragonal-pyramidal coordination polyhedron. The molecules of both complexes in crystal structures are linked by O-H center dot center dot center dot O hydrogen bonds, which created a three-dimensional hydrogen-bonding networks.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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