Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39894723" target="_blank" >RIV/00216275:25310/12:39894723 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.08.003" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2012.08.003</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2012.08.003" target="_blank" >10.1016/j.jorganchem.2012.08.003</a>

Result language

angličtina

Original language name

Phosphinimine complex of organotin(IV) compounds stabilized by O,C,O - chelating ligand

Original language description

Oxidation of an intramolecularly coordinated phosphine ligand {2,6-((BuOCH2)-Bu-t)(2)C6H3}PPh2 (1) by Me3SiN3 provided novel silyl-phosphinimine {2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NSiMe3 (2), that can be easily hydrolysed to give stable phosphiniminium azide [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH2](+) N-3(-) (3). Compound 3 was used for the synthesis of novel intramolecularly coordinated phosphinimine compound (LPh2P)-Ph-1=NH, that can be trapped by triorganotin(IV) compounds R3SnCl (R = Me, Cy) as organotin(IV)-phosphinimine complexes [{2,6-((BuOCH2)-Bu-t)(2)C6H3}Ph2P=NH]SnR3Cl (R = Me(4), Cy(5)). Compounds 2-5 were characterized by means of elemental analyses, H-1, C-13, P-31, Sn-119 NMR spectroscopy, and compounds 3 and 4 by single crystal X-ray diffraction analysis.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

718

Issue of the periodical within the volume

November

Country of publishing house

CH - SWITZERLAND

Number of pages

5

Pages from-to

38-42

UT code for WoS article

000309516000006

EID of the result in the Scopus database

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