Stabilization of an Intramolecularly Coordinated Stannylidenium Cation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39894827" target="_blank" >RIV/00216275:25310/12:39894827 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/zaac.201200064" target="_blank" >http://dx.doi.org/10.1002/zaac.201200064</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/zaac.201200064" target="_blank" >10.1002/zaac.201200064</a>
Alternative languages
Result language
angličtina
Original language name
Stabilization of an Intramolecularly Coordinated Stannylidenium Cation
Original language description
The treatment of trans-{[2, 6-(Me2NCH2)2C6H3]SnI}2PtI2 with Na(pyt) (pyt = 2-mercaptopyridine) yielded the unprecedented complex {{[2, 6-(Me2NCH2)2C6H3]Sn}Pt(mu-pyt)2I} (1), where a Sn?N coordinated stannylidenium (LSnII)+ fragment donates a to a [PtII(pyt)2I] anion. Compound 1 was characterized by NMR spectroscopy and molecular structure was determined by X-ray diffraction analysis. The bonding situation in 1 was analyzed by DFT studies.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für anorganische und allgemeine Chemie
ISSN
0044-2313
e-ISSN
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Volume of the periodical
638
Issue of the periodical within the volume
11
Country of publishing house
DE - GERMANY
Number of pages
4
Pages from-to
1672-1675
UT code for WoS article
000308991600004
EID of the result in the Scopus database
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