Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895564" target="_blank" >RIV/00216275:25310/12:39895564 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om201025d" target="_blank" >http://dx.doi.org/10.1021/om201025d</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om201025d" target="_blank" >10.1021/om201025d</a>
Alternative languages
Result language
angličtina
Original language name
Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic
Original language description
Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable insolution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP106%2F10%2F0443" target="_blank" >GAP106/10/0443: Organometallic chalcogenides of 14 and 15 group as nanodimensional and MOCVD materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
31
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
1725-1729
UT code for WoS article
000301331200019
EID of the result in the Scopus database
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