Codeposited Antimony-Bismuth Film Carbon Paste Electrodes for Electrochemical Stripping Determination of Trace Heavy Metals
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896382" target="_blank" >RIV/00216275:25310/13:39896382 - isvavai.cz</a>
Result on the web
<a href="http://www.electrochemsci.org/papers/vol8/80202095.pdf" target="_blank" >http://www.electrochemsci.org/papers/vol8/80202095.pdf</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Codeposited Antimony-Bismuth Film Carbon Paste Electrodes for Electrochemical Stripping Determination of Trace Heavy Metals
Original language description
Applying synergic electroplatting of antimony and bismuth at the carbon paste electrode substrates, new types of film electrodes were obtained allowing the determination of cadmium(II) and lead(II) ions at the microgram-per-liter concentration levels, when using square-wave anodic stripping voltammetric protocol. Compared with electrodes electroplated by individual metals, current responses obtained within reoxidation of both metal ions tested were favourably higher when related with measurements at codeposited films. In solutions of hydrochloric acid (0.01 - 1.0 mol L-1), an optimum concentration ratio c(Sb)/[c(Sb)+c(Bi)] was around 0.7 when in situ electrodeposition was applied and around 0.8 at ex situ platting. Formation of intermetallic compoundswas confirmed by both microstructural and elemental analyses.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LC06035" target="_blank" >LC06035: Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Electrochemical Science
ISSN
1452-3981
e-ISSN
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Volume of the periodical
8
Issue of the periodical within the volume
2
Country of publishing house
CS - SERBIA AND MONTENEGRO
Number of pages
9
Pages from-to
2095-2103
UT code for WoS article
000316565800048
EID of the result in the Scopus database
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